Illustrator CS3 - Print - Output - Wont allow me to select Separations


hi there

 

i'm silkscreening first time.  prepping process should simple right?  separate colour layers, using illustrator, print each layer onto transparency sheets.  i'm loose mind.

 

the image cmyk, single spot colour (i think) red , outlines black.  printer canon ix6500.

 

i can't seem separate colours in illustrator cs3?!  why?!  when selecting print > output > mode > won't allow me select colour separations.

 

i've tried overcome selecting printer > adobe postscript , ppd > canon ix6500 series.  allows me select colour separations, won't print, saves pdf, , prints is.

 

please help!!!  advice appreciated!!  i'm going out of mind here!!

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